WebJul 15, 2015 · Abstract Anion receptors based on a [CpFe(indenyl)] scaffold offer the possibility for the incorporation of adjacent Lewis acidic functions onto a six-membered carbocyclic framework, while at the s... WebFeb 27, 2015 · A single-component ambiphilic system capable of the cooperative activation of protic, hydridic and apolar H X bonds across a Group 13 metal/activated β-diketiminato …

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Rémi TIRFOIN Postdoctoral DPhil in inorganic chemistry (oxon ...

WebDec 3, 2015 · An extremely bulky boryl-amide ligand, [N(SiMe 3){B(DAB)}] − (TBoN; DAB = (DipNCH) 2, Dip = C 6 H 3 Pr i 2-2,6), has been utilised in the preparation of the first … WebReactions of the β-diketiminato (‘Nacnac’) stabilized gallium dihydride H 2 Ga{(NDippCMe) 2 CH} with a range of mono- and dinuclear metal carbonyl reagents are characterized by loss of dihydrogen and formation of donor/acceptor complexes featuring the Ga(I) carbenoid ligand : Ga{(NDippCMe) 2 CH}. Thus, far from simply mimicking the chemistry of the … WebMay 7, 2008 · The total structure determination of thiol-protected Au clusters has long been a major issue in cluster research. Herein, we report an unusual single crystal structure of a 25-gold-atom cluster (1.27 nm diameter, surface-to-surface distance) protected by eighteen phenylethanethiol ligands. cuttle lake ontario